ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

Base Information

Chemical Name:ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate
CAS No.:114182-19-3
Molecular Formula:C₁₃H₁₄O₂
Molecular Weight:202.253
Hs Code.:

ethyl endo-3-tricyclo<4.4.0.0<sup>2,4</sup>>deca-1(6),7,9-trienecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

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Technology Process of ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

There total 2 articles about ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 95-13-6
1-indene

: 59875-31-9,59905-91-8,59905-96-3,59953-45-6,72258-13-0,114180-54-0,114182-19-3
ethyl exo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

: 59875-31-9,59905-91-8,59905-96-3,59953-45-6,72258-13-0,114180-54-0,114182-19-3
ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

: 623-91-6
diethyl Fumarate

: 141-05-9
Diethyl maleate

Guidance literature:: 1,4,7,10,17,20,23,26-octaoxa-16,32-(1,10-phenantholin-2,9-diyl)-<10.10>metacyclophane; copper(I) triflate; In dichloromethane; 1,2-dichloro-ethane; at 20 ℃; for 24h; Yield given. Yields of byproduct given;
DOI:10.1002/cber.19971300215

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 95-13-6
1-indene

: 59875-31-9,59905-91-8,59905-96-3,59953-45-6,72258-13-0,114180-54-0,114182-19-3
ethyl exo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

: 59875-31-9,59905-91-8,59905-96-3,59953-45-6,72258-13-0,114180-54-0,114182-19-3
ethyl endo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

: 623-91-6
diethyl Fumarate

: 141-05-9
Diethyl maleate

Guidance literature:: 1,4,7,10,17,20,23,26-octaoxa-16,32-(1,10-phenantholin-2,9-diyl)-<10.10>metacyclophane; copper(I) triflate; In dichloromethane; 1,2-dichloro-ethane; at 20 ℃; for 24h; Yield given. Yields of byproduct given;
DOI:10.1002/cber.19971300215

Reference yield:

: 59875-31-9,59905-91-8,59905-96-3,59953-45-6,72258-13-0,114180-54-0,114182-19-3
ethyl exo-3-tricyclo<4.4.0.0^2,4>deca-1(6),7,9-trienecarboxylate

: (S)-4-phenyl-3-((1S,1aS,6aR)-1,1a,6,6a-tetrahydrocyclopropa[a]indene-1-carbonyl)oxazolidin-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydroxide / methanol / 50 °C

2.1: isopropyl alcohol; hexane / UV-irradiation; Resolution of racemate

3.1: triethylamine; pivaloyl chloride / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

With pivaloyl chloride; triethylamine; sodium hydroxide; In tetrahydrofuran; methanol; hexane; isopropyl alcohol;
DOI:10.1016/j.ejmech.2017.09.073