(CO)2Fe(P(CH₃)2C₆H₅)2I₂

Base Information

• Chemical Name: (CO)2Fe(P(CH₃)2C₆H₅)2I₂
• CAS No.: 25226-45-3
• Molecular Formula: C₁₈H₂₂FeI₂O₂P₂
• Molecular Weight: 641.975
• Mol file: 25226-45-3.mol

Synonyms:

Chemical Property of (CO)2Fe(P(CH₃)2C₆H₅)2I₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (CO)2Fe(P(CH₃)2C₆H₅)2I₂

There total 5 articles about (CO)2Fe(P(CH₃)2C₆H₅)2I₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(CO)2Fe(P(CH3)2C6H5)2 → (CO)2Fe(P(CH3)2C6H5)2I2 (25226-45-3)

Guidance literature:

With I₂; In hexane; equimolar ratio of educts; recrystn. from CH2Cl2/C6H14 at -78°C;

DOI:10.1039/J19690002645

Reference yield:

diiodotetracarbonyliron(II) (15616-56-5,14911-55-8,14878-30-9) + Dimethyl(phenyl)phosphine (672-66-2) → Fe(CO)3(PMe2Ph)2 (52253-91-5) + fac-Fe(CO)3I2(PMe2Ph) (911420-35-4) + cis,trans,cis-Fe(CO)2I2(PMe2Ph)2 (25226-45-3)

Guidance literature:

In toluene; byproducts: (P(CH3)2(C6H5)I)I; under N2 atm. using Schlenk techniques; Fe complex dissolved in toluene;soln. injected in thermostatted and blackened reactor (temp. was from - 40 to 25°C); phosphine (1.5E-1 to E-2 M) added; not isolated; monitored by IR spectroscopy;

DOI:10.1016/j.jorganchem.2006.05.041

Reference yield:

Fe(CO)3(PMe2Ph)2 (52253-91-5) + iodine (7553-56-2,12190-71-5,8031-47-8) → (CO)2Fe(P(CH3)2C6H5)2I2 (25226-45-3)

Guidance literature:

DOI:10.1039/J19690002645

upstream raw materials:

Fe(CO)3(PMe2Ph)2

iodine

hydrogen iodide

Dimethyl(phenyl)phosphine