Technology Process of [Ru(2,6-dimethylthiophenol)4(MeCN)]
There total 1 articles about [Ru(2,6-dimethylthiophenol)4(MeCN)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
NaOMe;
In
methanol; acetonitrile;
ligand and NaOMe were added to slurry of Ru-complex in MeOH/MeCN, refluxed for 8 h, cooled to room temp. under N2; solvent was removed under vac., washed with hexane and Et2O, extd. with CHCl3, Et2O was layered, cooled to -10°C, recrystd. from CH2Cl2/EtOH/Et2O, column chromy. on silica gel with CH2Cl2/acetone; elem. anal.;
DOI:10.1021/om011019t
- Guidance literature:
-
In
tetrahydrofuran; diethyl ether;
soln. of HCl in Et2O was added to soln. of Ru-complex in THF, stirred overnight at room temp. under N2; solvent was pumped off, washed with hexane and Et2O, recrystd. from CH2Cl2/Et2O; elem. anal.;
DOI:10.1021/om011019t
