ReH₃(P(C₆H₅)3)3(NCCH₃)

Base Information

• Chemical Name: ReH₃(P(C₆H₅)3)3(NCCH₃)
• CAS No.: 108530-77-4
• Molecular Formula: C₅₆H₅₁NP₃Re
• Molecular Weight: 1017.16

Synonyms:

Chemical Property of ReH₃(P(C₆H₅)3)3(NCCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ReH₃(P(C₆H₅)3)3(NCCH₃)

There total 2 articles about ReH₃(P(C₆H₅)3)3(NCCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

pentahydridotris(triphenylphosphane)Re(V) (12104-75-5,122169-15-7) + tropylium hexafluorophosphate (29663-54-5) + acetonitrile (75-05-8,26809-02-9) → ReH3(P(C6H5)3)3(NCCH3) (108530-77-4)

Guidance literature:

With triethyl amine; In acetonitrile; A mixt. of reagents in CH3CN was stirred for 5 min, Et3N was added and stirred for 30 min (N2 atm.);; ppt. was filtered off and washed with CH3CN;;

DOI:10.1039/DT9870000715

Reference yield: 52.0%

ReH4(P(C6H5)3)4(1+)*PF6(1-)={ReH4(P(C6H5)3)4}PF6 (108547-90-6) + acetonitrile (75-05-8,26809-02-9) → ReH3(P(C6H5)3)3(NCCH3) (108530-77-4)

Guidance literature:

With triethyl amine; In acetonitrile; A soln. of complex in CH3CN and Et3N was stirred for 3 h (N2 atm.);; ppt. was filtered off, washed with CH3CN; elem. anal.;;

DOI:10.1039/DT9870000715

Reference yield: 78.0%

ReH3(P(C6H5)3)3(NCCH3) (108530-77-4) + tropylium hexafluorophosphate (29663-54-5) + acetonitrile (75-05-8,26809-02-9) → ReH(P(C6H5)3)3(NCCH3)3(2+)*2(PF6)(1-)={ReH(P(C6H5)3)3(NCCH3)3}(PF6)2 + ReH2(P(C6H5)3)3(NCCH3)2(1+)*PF6(1-)={ReH2(P(C6H5)3)3(NCCH3)2}PF6 (108530-75-2)

Guidance literature:

In diethyl ether; A mixt. of reagents was added to a Et2O contained a small quantity of CH3CN, the mixt. was stirred for 45 min (N2 atm.);; ppt. was filtered off, washed with Et2O; elem. anal.;;

DOI:10.1039/DT9870000715

upstream raw materials:

ReH₄(P(C₆H₅)3)4⁽¹⁺⁾*PF₆^(1-)={ReH₄(P(C₆H₅)3)4}PF₆

acetonitrile

pentahydridotris(triphenylphosphane)Re(V)

tropylium hexafluorophosphate

Downstream raw materials:

ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 108530-77-4 ReH₃(P(C₆H₅)3)3(NCCH₃)

Send

Send

Metric Ton KG G Pound L ML

Send

Send