trans-PtCl₂(PPh(OEt)2)2

Base Information

Chemical Name:trans-PtCl₂(PPh(OEt)2)2
CAS No.:51466-25-2
Molecular Formula:C₂₀H₃₀Cl₂O₄P₂Pt
Molecular Weight:662.389
Hs Code.:

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Chemical Property of trans-PtCl₂(PPh(OEt)2)2

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Technology Process of trans-PtCl₂(PPh(OEt)2)2

There total 1 articles about trans-PtCl₂(PPh(OEt)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 107002-51-7,186417-85-6,148684-65-5
cis-bis(p-tolunitrile)dichloroplatinum(II)

: 1638-86-4
diethyl phenylphosphonite

: 54274-98-5,51466-25-2,864069-79-4
trans-PtCl₂(PPh(OEt)2)2

Guidance literature:: In dichloromethane; under N2 or Ar; PPh(OEt)2 (excess) added to soln. of Pt complex in CH2Cl2; stirred for 24 h; solvent removed under reduced pressure; oil triturated with EtOH; filtered; ppt. crystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1039/b505453b

Reference yield: 70.0%

: 54274-98-5,51466-25-2,864069-79-4
trans-PtCl₂(PPh(OEt)2)2

: 143-66-8
sodium tetraphenyl borate

: 302-01-2,78206-91-4,119775-10-9,75013-58-0
hydrazine

: 863982-74-5
cis-[PtCl(hydrazine)(PPh(PEt)2)2]BPh₄

Guidance literature:: With silver triflate; In dichloromethane; byproducts: AgCl; under N2 or Ar; CH2Cl2 added to Pt complex and AgSO3CF3; stirred in the dark for 24 h; filtered; filtrate cooled to -196°C; NH2NH2 (excess) added; stirred (room temp., 8 h); solvent removed under reduced pressure; treated with EtOH contg. NaBPh4; filtered; solid crystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1039/b505453b

Reference yield: 70.0%

: 16940-66-2
sodium tetrahydroborate

: 54274-98-5,51466-25-2,864069-79-4
trans-PtCl₂(PPh(OEt)2)2

: 863982-69-8
trans-PtHCl(PPh(OEt)2)2

Guidance literature:: In acetonitrile; under N2 or Ar; soln. of NaBH4 (1 equiv.) in MeCN added to soln. of Pt complex in MeCN at -196°C; brought to room temp.; stirred for 4 h; solvent removed under reduced pressure; extd. with benzene-petroleum ether; extracts evapd. to dryness; oil treated with benzene and Et2O; cooled to -25°C; solid isolated by filtration; elem. anal.;
DOI:10.1039/b505453b