dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II)

Base Information

• Chemical Name: dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II)
• CAS No.: 827043-35-6
• Molecular Formula: C₁₉H₂₆Cl₂O₂P₂Pd
• Molecular Weight: 525.688
• Mol file: 827043-35-6.mol

Synonyms:

Chemical Property of dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II)

There total 1 articles about dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + 1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane (826990-03-8) → dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II) (827043-35-6,827036-91-9)

Guidance literature:

In dichloromethane; (Ar), ligand in CH2Cl2 added to Pd complex in CH2Cl2, stirred for 1 h; separated, washed (CH2Cl2, pentane), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200300903

Reference yield: 89.0%

silver tetrafluoroborate (14104-20-2) + dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II) (827043-35-6,827036-91-9) + acetonitrile (75-05-8,26809-02-9) → diacetonitrile[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II) ditetrafluoroborate

Guidance literature:

In acetonitrile; (Ar), AgBF4 added to suspn. of Pd complex in CH3CN, stirred for 1 h; filtered, concd.(vac.), filtered, pptd.(ether), washed (diethyl ether, n-pentane), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200300903

Reference yield: 23.0%

dichloro[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]palladium(II) (827043-35-6,827036-91-9) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → [1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]diiodopalladium(II) (827036-92-0,827043-34-5) + (PS,P'R)-[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]diiodopalladium(II) (827036-92-0,827043-34-5)

Guidance literature:

In dimethyl sulfoxide; (Ar), Pd complex in DMSO treated with NaI, stirred for 15 h at room temp.; extd.(ether), extd.(CH2Cl2, acetone), crystd., chromy.(silica - CH2Cl2/acetone 1:2), crystd., elem. anal.;

DOI:10.1002/ejic.200300903

upstream raw materials:

dichloro(1,5-cyclooctadiene)palladium(II)

1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane

Downstream raw materials:

[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]diiodopalladium(II)

(PS,P'R)-[1,3-bis[(2-hydroxyethyl)(phenyl)phosphanyl]propane]diiodopalladium(II)