[OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

Base Information

Chemical Name:[OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6
CAS No.:791633-65-3
Molecular Formula:C₂₁H₃₀OsP*F₆P
Molecular Weight:648.607
Hs Code.:

Synonyms:

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Chemical Property of [OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

Chemical Property:

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Technology Process of [OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

There total 4 articles about [OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 60969-19-9
thallium(I) hexafluorophosphate

: 791633-63-1
Os(η5-C5H5)Cl(P(i)Pr2[C(CH3)CH2CHPh])

: 791633-65-3,791633-67-5
[OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

Guidance literature:: In acetone; byproducts: TlCl; under inert atm. soln. Os complex in acetone was treated with TlPF6 andstirred for 15 min in the absence of light, filtered, cooled to -50.deg ree.C, Et2O was added, suspn. ppt. in THF was refluxed for 30 h; solvent was removed in vacuo, residue was dissolved in acetone and cooled to 0°C, Et2O was added; elem. anal.;
DOI:10.1021/om0496075

Reference yield:

: [OsH(η5-C5H5)(CPh)(P(i)Pr2[C(CH3)=CH2])]PF6

: 791633-65-3,791633-67-5
[OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

Guidance literature:: In dichloromethane; under inert atm. soln. Os complex in CH2Cl2 was stirred at room temp. for 40 h; soln. was filtered through Kieselguhr and concd., Et2O was added, ppt. was washed with Et2O and dried in vacuo;
DOI:10.1021/om0496075

Reference yield:

: 60969-19-9
thallium(I) hexafluorophosphate

: 791633-63-1
Os(η5-C5H5)Cl(P(i)Pr2[C(CH3)CH2CHPh])

: 791633-65-3,791633-67-5
[OsH(η5-C5H5)Cl([η3-C6H5CHCH=C(CH3)]P(i)Pr2)]PF6

: 791633-65-3,791633-67-5
[OsH(η5-C5H5)Cl([η3-CHPhCHC(CH3)]P(i)Pr2)]PF6

Guidance literature:: In acetone; byproducts: TlCl; under inert atm. soln. Os complex in acetone was treated with TlPF6 andstirred for 15 min in the absence of light; react. mixt. was filtered through Kieselguhr, soln. was concd. and cooled to -50°C, Et2O was added, ppt. was washed with Et2O and dried in vacuo;
DOI:10.1021/om0496075