1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Base Information

Chemical Name:1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene
CAS No.:198059-84-6
Molecular Formula:C₂₇H₂₆FeO
Molecular Weight:422.35
Hs Code.:

Synonyms:

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Chemical Property of 1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

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Technology Process of 1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

There total 2 articles about 1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 611-94-9
4-Methoxybenzophenone

: propionylferrocene

: 198059-83-5,198059-84-6
1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Guidance literature:: With TiCl₄; Zn; In tetrahydrofuran; Ar-atmosphere; dropwise addn. of 2 equiv. Zn to TiCl4 at -10°C, refluxing for 2.5 h, cooling to 18°C, dropwise addn. of mixt. of 0.2 equiv. of Fe-complex and 1 equiv. of methoxybenzophenone, heating for15 h; addn. of 10% aq. K2CO3, extn. into ether, solvent removal, chromy. (SiO2, ethyl acetate/pentane=1:20);
DOI:10.1016/S0022-328X(97)00086-7

Reference yield: 37.0%

: 108-86-1,52753-63-6
bromobenzene

: 198059-82-4
[(ferrocenyl)propyl](4-methoxyphenyl)ketone

: 198059-83-5,198059-84-6
1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Guidance literature:: With Li; In diethyl ether; Ar-atmosphere; addn. of 2 equiv. Li to PhBr, cooling to 0°C, dropwise addn. of 0.5 equiv. of Fe-complex soln., stirring for 1 h, slow warming to room temp.; evapn., addn. of EtOH and concd. HCl, stirring for 5 min, pouring into ice water, extn. into ether, washing of org. phase (H2O), drying (MgSO4),filtration, solvent removal, chromy. (SiO2, ether/pentane=2:7); elem. a nal.; isomers separable by crystn.;
DOI:10.1016/S0022-328X(97)00086-7

Reference yield:

: 198059-83-5,198059-84-6
1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

: 878277-53-3,198059-86-8,198059-85-7
1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Guidance literature:: With BBr₃; In dichloromethane; Ar-atmosphere; addn. of equimolar amt. of BBr3 to Fe-complex soln. at -78°C, stirring for 30 min and warming; pouring into ice water, stirring for 10 min, addn. of NaCl, extn. into CH2Cl2, washing of org. phase (aq. Na2S2O3, H2O), drying (MgSO4), filtration, solvent removal, crystn.;
DOI:10.1016/S0022-328X(97)00086-7