(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Base Information

Chemical Name:(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane
CAS No.:119447-85-7
Molecular Formula:C₅₃H₅₄O₉S
Molecular Weight:867.072
Hs Code.:

(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

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Chemical Property of (2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

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Technology Process of (2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

There total 7 articles about (2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 119447-85-7,119447-86-8
(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Guidance literature:: Multi-step reaction with 3 steps

1: 2.) Na₂CO₃ / 1.) CCl₄, room temp., 2.) THF, H₂O, room temp., 0.5 h; room temp. to 50 deg C, 1 h

2: 70 percent / NaH / CH₂Cl₂ / Ambient temperature

3: 1.) molecular sieves 4 Angstroem, 2.) BF₃*Et₂O / 1.) CH₂Cl₂, room temp., 30 min, 2.) Et₂O, CH₂Cl₂, -95 deg C, 15 min

With 4 A molecular sieve; boron trifluoride diethyl etherate; sodium hydride; sodium carbonate; In dichloromethane;
DOI:10.1055/s-1988-27673

Reference yield:

: 117901-42-5
3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranose

: 119447-85-7,119447-86-8
(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / NaH / CH₂Cl₂ / Ambient temperature

2: 1.) molecular sieves 4 Angstroem, 2.) BF₃*Et₂O / 1.) CH₂Cl₂, room temp., 30 min, 2.) Et₂O, CH₂Cl₂, -95 deg C, 15 min

With 4 A molecular sieve; boron trifluoride diethyl etherate; sodium hydride; In dichloromethane;
DOI:10.1055/s-1988-27673

Reference yield:

: 117901-42-5
3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranose

: 119447-85-7,119447-86-8
(2R,3S,4R)-3,4-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / NaH / CH₂Cl₂ / Ambient temperature

2: 1.) molecular sieves 4 Angstroem, 2.) BF₃*Et₂O / 1.) CH₂Cl₂, room temp., 30 min, 2.) Et₂O, CH₂Cl₂, -95 deg C, 15 min

With 4 A molecular sieve; boron trifluoride diethyl etherate; sodium hydride; In dichloromethane;
DOI:10.1055/s-1988-27673