Technology Process of (η5-C5H5)Fe(CO)(PPh3)COCH2SePh
There total 1 articles about (η5-C5H5)Fe(CO)(PPh3)COCH2SePh which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran; hexane;
ubder N2 atm. to soln. Fe complex in THF at -78°C n-BuLi in hexane was added, after 2 h soln. PhSeSePh in THF was added and stirred for 1h; MeOH was added, react. mixt. was warmed to room temp., concd. in vacuo, residue was extd. with CH2Cl2, filtered through alumina V, filtrate was evapd., residue was purified by chromy. on silica (Et2O-pet.ether), crystn. from CH2Cl2-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2004.04.046
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran; hexane;
under N2 atm. to soln. Fe complex in THF acid at -78°C n-BuLi in hexane was added, allyl iodide was added after 2 h, react. mixt. was allowed to warm to room temp. over 16 h; soln. was concd. in vacuo, residue was extd. with CH2Cl2 and filtered through alumina V, solvent was removed, chromy. on silica (Et2O-pet.ether)and crystn. from CH2Cl2-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2004.04.046
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran; hexane;
ubder N2 atm. to soln. Fe complex in THF at -78°C n-BuLi in hexane was added, after 1 h MeI was added, allowed to warm to room temp. and stirred for 4 h; solvent was removed in vacuo, residue was extd. with CH2Cl2 and filteredthrough alumina V, filtrate was concd., residue was purified by chromy. on alumina; diastereomers were not separated;
DOI:10.1016/j.jorganchem.2004.04.046
