triphenylphosphinegold(I) hexafluorophosphate

Base Information

• Chemical Name: triphenylphosphinegold(I) hexafluorophosphate
• CAS No.: 83214-85-1
• Molecular Formula: C₁₈H₁₅AuP*F₆P
• Molecular Weight: 604.222
• Mol file: 83214-85-1.mol

Synonyms:

Chemical Property of triphenylphosphinegold(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylphosphinegold(I) hexafluorophosphate

There total 5 articles about triphenylphosphinegold(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

potassium hexafluorophosphate (17084-13-8) + (triphenylphosphine)gold(I) nitrate (14897-32-6) → triphenylphosphinegold(I) hexafluorophosphate (83214-85-1)

Guidance literature:

In methanol; acetonitrile; addition of a solution of Ph3PAuNO3 in a small amount of MeOH/MeCN (2:1) to a 4-fold amount of a saturated solution of KPF6 in MeOH under N2;; extraction with CH2Cl2 and evaporation;;

Reference yield:

silver(I) hexafluorophosphate (26042-63-7) + (triphenylphosphine)gold(I) chloride (14243-64-2) → triphenylphosphinegold(I) hexafluorophosphate (83214-85-1)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/om960148k

Reference yield:

silver(I) hexafluorophosphate (26042-63-7) + (triphenylphosphine)gold(I) chloride (14243-64-2) → Au(PPh3)hexafluorophosphate (83214-85-1)

Guidance literature:

In methanol; To a soln. of AgPF6 in CH3OH is added a soln. of AuCl(PPh3) in acetone.;

upstream raw materials:

silver(I) hexafluorophosphate

(triphenylphosphine)gold(I) chloride

thallium(I) hexafluorophosphate

chlorotriphenylphosphinegold(I)

Downstream raw materials:

[(2-(2-pyridyl)benzimidazole)Au(triphenylphosphine)][PF₆]

[(triphenylphosphine)Au(μ-2-(2-pyridyl)benzimidazolato)Au(triphenylphosphine)][PF6]

platinum(methyl)2(2,2'-bipyridine)gold(PPh₃)}PF₆

Refernces

• 1、 Antinolo, Antonio,Jalon, Felix A.,Otero, Antonio,Fajardo, Mariano,Chaudret, Bruno,et al.. "Reactivity of Ruthenium and Niobium Trihydrides with Gold Fragments. Crystal Structure of the Hexanuclear Raft Cluster ". . p. 1861 - 1866. Retrieved 1991.
• 2、 Arsenault, Gilles J.,Anderson, Craig M.,Puddephatt, Richard J.. "Complexes with PtAu and PtAg bonds: Catalysis by silver(I) of alkyl exchange reactions between platinum centers". . p. 2094 - 2097. Retrieved 2008/10/08.