cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

Base Information

Chemical Name:cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)
CAS No.:268745-44-4
Molecular Formula:C₃₉H₄₆Cl₂N₃PRu
Molecular Weight:759.764
Hs Code.:

cis-RuCl<sub>2</sub>(PPh<sub>3</sub>)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

Synonyms:

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Chemical Property of cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

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Technology Process of cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

There total 2 articles about cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 204856-92-8
2,6-bis[1-(cyclohexylphenylimino)ethyl]pyridine

: 268745-44-4
cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

Guidance literature:: In acetone; acetone soln. contg. 2,6-py(NCy)2 and RuCl2(PPh3)3 was refluxed under N2 for 4 h; soln. was concd., Et2O was slowly added, solid was filtered, washed with Et2O and dried under a stream of N2, elem. anal.;
DOI:10.1021/om990951p

Reference yield:

: 268745-45-5
trans-RuCl2(η(2)-ethylidene)(2,6-bis[1-(cyclohexylimine)ethyl]pyridine)

: 603-35-0
triphenylphosphine

: 268745-44-4
cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

Guidance literature:: In dichloromethane-d2; byproducts: C2H4; stoich. amt. of PPh3 was added to Ru complex;
DOI:10.1021/om990951p

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 268745-44-4
cis-RuCl₂(PPh₃)(2,6-bis[1-(cylohexylimine)ethyl]pyridine)

: trans-RuCl₂(=CHCO₂Et)(2,6-bis[1-(cyclohexylimine)ethyl]pyridine)

: cis-RuCl₂(=CHCO₂Et)(2,6-bis[1-(phenylimine)ethyl]pyridine)

Guidance literature:: In dichloromethane-d2; byproducts: Ph3PCHCO2Et; under N2, at -80°C, cis-isomer concn. was decreasing with increasing the temp. to -50°C; detected by 1H-NMR;
DOI:10.1021/om990951p