[2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate

Base Information

• Chemical Name: [2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate
• CAS No.: 334474-91-8
• Molecular Formula: C₄₁H₄₃N₈O₁₇P₂Zn₂*ClO₄
• Molecular Weight: 1212.01
• Mol file: 334474-91-8.mol

Synonyms:

Chemical Property of [2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate

There total 1 articles about [2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

zinc perchlorate + sodium bis(4-nitrophenyl) phosphate (4043-96-3) + 2,6-bis((E)-((2-(dimethylamino)ethyl)imino)methyl)-4-methylphenol → [2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate (334474-91-8)

Guidance literature:

In methanol; Zn salt added to a soln. of the ligand; stirred at 60°C for 30 min; soln. of NaBNP added; concd.; crystals collected; identified by elem. anal.;

DOI:10.1246/bcsj.74.85

Reference yield:

[2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate (334474-91-8) → Zn2(((CH3)2N(CH2)2NCH)2C6H2CH3O)(3+) + bis(4-nitrophenyl)phosphate ion (7279-71-2)

Guidance literature:

In N,N-dimethyl-formamide; dissolving in DMF; monitored by (31)P NMR;

DOI:10.1246/bcsj.74.85

Reference yield:

[2,6-bis[N-[2-(dimethylamino)ethyl]iminomethyl]-4-methylphenolato]di[μ-bis(4-nitrophenyl)phosphato]dizinc(II) perchlorate (334474-91-8) → Zn2(((CH3)2N(CH2)2NCH)2C6H2CH3O)((NO2C6H4O)2PO2)(2+) + bis(4-nitrophenyl)phosphate ion (7279-71-2)

Guidance literature:

In N,N-dimethyl-formamide; dissolving in DMF; monitored by (31)P NMR;

DOI:10.1246/bcsj.74.85

upstream raw materials:

sodium bis(4-nitrophenyl) phosphate

Downstream raw materials:

bis(4-nitrophenyl)phosphate ion