trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF₆

Base Information

• Chemical Name: trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF₆
• CAS No.: 1244032-54-9
• Molecular Formula: C₃₉H₃₆ClN₂OP₂Ru*F₆P
• Molecular Weight: 892.162

Synonyms:

Chemical Property of trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF₆

Chemical Property:

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Technology Process of trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF₆

There total 1 articles about trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[2,2]bipyridinyl (366-18-7) + ammonium hexafluorophosphate + [Ru2Cl4(carbon monoxide)2(1,4-bis(diphenylphosphino)butane)3] → trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF6 (1243693-36-8,1244032-54-9)

Guidance literature:

In dichloromethane; (Ar); refluxing a mixt. of Ru complex, ligand and NH4PF6 in CH2Cl2 for 6h; concn., addn. of ether, washing ppt. with water, ether, drying in vac.; elem. anal.;

DOI:10.1016/j.poly.2010.04.028

Reference yield: 86.0%

trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF6 (1243693-36-8,1244032-54-9) → cc-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF6

Guidance literature:

In methanol; dichloromethane; (Ar); refluxing a soln. of Ru complex in CH2Cl2 and methanol for 24 h; concn., addn. of ether, filtration, washing ppt. with ether, drying in vac.; elem. anal.;

DOI:10.1016/j.poly.2010.04.028

Reference yield: 65.0%

pyridine (110-86-1) + trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF6 (1243693-36-8,1244032-54-9) → trans,cis-[RuCl(pyridine)(1,4-bis(diphenylphosphino)butane)(2,2'-bipyridine)]PF6

Guidance literature:

With NH₄PF₆; In acetonitrile; Electrolysis; (Ar); electrolysis of a soln. of Ru complex in acetonitrile at 2.1 V in the presence of pyridine and NH4PF6, then electrolysis at 0.7 V; concn., addn. of ether, washing ppt. with water, ether, drying in vac.; elem. anal.;

DOI:10.1016/j.poly.2010.04.028

upstream raw materials:

[2,2]bipyridinyl

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