Technology Process of 2,9-di-tert-butyl-7,14-diphenyl-5,12-dithiapentacene
There total 4 articles about 2,9-di-tert-butyl-7,14-diphenyl-5,12-dithiapentacene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: thionyl chloride / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere
2: titanium tetrachloride / dichloromethane / 20 °C
3: tetrahydrofuran
4: tin(ll) chloride; hydrogenchloride / tetrahydrofuran; water / 0.5 h
With
hydrogenchloride; thionyl chloride; titanium tetrachloride; tin(ll) chloride;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
2: |Friedel-Crafts Acylation;
DOI:10.1021/ol5017756
- Guidance literature:
-
Multi-step reaction with 3 steps
1: titanium tetrachloride / dichloromethane / 20 °C
2: tetrahydrofuran
3: tin(ll) chloride; hydrogenchloride / tetrahydrofuran; water / 0.5 h
With
hydrogenchloride; titanium tetrachloride; tin(ll) chloride;
In
tetrahydrofuran; dichloromethane; water;
1: |Friedel-Crafts Acylation;
DOI:10.1021/ol5017756
- Guidance literature:
-
Multi-step reaction with 6 steps
1: potassium carbonate / N,N-dimethyl-formamide / 120 °C / Inert atmosphere
2: water; sodium hydroxide / tetrahydrofuran; ethanol / 70 °C
3: thionyl chloride / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere
4: titanium tetrachloride / dichloromethane / 20 °C
5: tetrahydrofuran
6: tin(ll) chloride; hydrogenchloride / tetrahydrofuran; water / 0.5 h
With
hydrogenchloride; thionyl chloride; water; titanium tetrachloride; potassium carbonate; tin(ll) chloride; sodium hydroxide;
In
tetrahydrofuran; ethanol; dichloromethane; water; N,N-dimethyl-formamide;
4: |Friedel-Crafts Acylation;
DOI:10.1021/ol5017756
