2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene

Base Information

• Chemical Name: 2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene
• CAS No.: 106923-13-1
• Molecular Formula: C₄₉H₄₅FeNSn₂
• Molecular Weight: 941.17
• Mol file: 106923-13-1.mol

Synonyms:

Chemical Property of 2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene

There total 1 articles about 2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

N,N-dimethylaminomethylferrocene (1271-86-9) + triphenyltin chloride (639-58-7) → 2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene (106923-13-1)

Guidance literature:

With n-butyllithium; In hexane; N2 atm.; lithiation by n-C4H9Li (in presence of TMED); stirring (1 h/room temp.); addn. of (C6H5)3SnCl (in small portions); stirring for 10 h; soln. became red; addn. of water;; filtration; evapn. of orange soln.; chromy. (neutral alumina/CH2Cl2 - C2H5O(O)CCH3 10:1); elem. anal.;;

DOI:10.1016/0022-328X(86)82042-3

Reference yield: 65.0%

2,1'-bis(triphenylstannyl)dimethylaminomethylferrocene (106923-13-1) + methyl iodide (74-88-4) → [((C6H5)3SnC5H3CH2N(CH3)3)Fe(C5H4Sn(C6H5)3)](1+)*I(1-)=[C50H48FeNSn2]I (106923-14-2)

Guidance literature:

In benzene; addn. of CH3I to soln. in dry benzene; left at room temp. (2 h);; filtration; drying;;

DOI:10.1016/0022-328X(86)82042-3

upstream raw materials:

N,N-dimethylaminomethylferrocene

triphenyltin chloride

Downstream raw materials:

[((C₆H₅)3SnC₅H₃CH₂N(CH₃)3)Fe(C₅H₄Sn(C₆H₅)3)]⁽¹⁺⁾*I^(1-)=[C₅₀H₄₈FeNSn₂]I