[ruthenium(dichloride)(NH(2-PPh₂-4-Me-C₆H₃)2)]

Base Information

• Chemical Name: [ruthenium(dichloride)(NH(2-PPh₂-4-Me-C₆H₃)2)]
• CAS No.: 1263063-31-5
• Molecular Formula: C₃₈H₃₃Cl₂NP₂Ru
• Molecular Weight: 737.61
• Mol file: 1263063-31-5.mol

Synonyms:

Chemical Property of [ruthenium(dichloride)(NH(2-PPh₂-4-Me-C₆H₃)2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ruthenium(dichloride)(NH(2-PPh₂-4-Me-C₆H₃)2)]

There total 1 articles about [ruthenium(dichloride)(NH(2-PPh₂-4-Me-C₆H₃)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) + bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine (1011473-19-0) → [ruthenium(dichloride)(NH(2-PPh2-4-Me-C6H3)2)] (1263063-31-5)

Guidance literature:

In toluene; Schlenk or glove box techniques, under N2; mixt. of PNP(Ph)H and Ru complex (equimolar amounts) in toluene heated at 110°C for 24 h; ppt. filtered off, dried under vac., elem. anal.;

DOI:10.1016/j.ica.2010.07.040

Reference yield: 96.0%

sodium tetrahydroborate (16940-66-2) + [ruthenium(dichloride)(NH(2-PPh2-4-Me-C6H3)2)] (1263063-31-5) → [ruthenium(μ-H)(H2)(N(2-PPh2-4-Me-C6H3)2)]

Guidance literature:

In tetrahydrofuran; Schlenk or glove box techniques, under N2; mixt. of Ru complex (0.136 mmol) and NaBH4 (2.64 mmol) stirred at 80°C for 3 h; concd. in vac., residue dissolved in C6H6, filtered, volatiles removed under vac., elem. anal.;

DOI:10.1016/j.ica.2010.07.040

Reference yield: 65.0%

[ruthenium(dichloride)(NH(2-PPh2-4-Me-C6H3)2)] (1263063-31-5) + silver trifluoromethanesulfonate (2923-28-6) → [ruthenium(NH(2-PPh2-4-Me-C6H3)2)(triflate)2] (1263063-33-7)

Guidance literature:

In benzene; byproducts: AgCl; Schlenk or glove box techniques, under N2; mixt. of Ru complex (0.136 mmol) and Ag(OTf) (2.64 mmol) stirred at room temp. for 5 h; ppt. filtered off, filtrate evapd. to dryness, residue recrystd. from C6H6 at room temp., elem. anal.;

DOI:10.1016/j.ica.2010.07.040

upstream raw materials:

bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine

Downstream raw materials:

[ruthenium(NH(2-PPh₂-4-Me-C₆H₃)2)(triflate)2]