Re(TPP)Cl₃

Base Information

Chemical Name:Re(TPP)Cl₃
CAS No.:128709-60-4
Molecular Formula:C₄₄H₂₈Cl₃N₄Re
Molecular Weight:905.299
Hs Code.:

Synonyms:

Suppliers and Price of Re(TPP)Cl₃

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Re(TPP)Cl₃

Chemical Property:

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Technology Process of Re(TPP)Cl₃

There total 3 articles about Re(TPP)Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: rhenium pentachloride

: 128709-60-4
Re(TPP)Cl₃

: 128709-68-2
μ-oxo-bis[(oxo)-(5,10,15,20-tetraphenyl-21H,23H-porphinato)rhenium(V)]

Guidance literature:: With potassium hydroxide; In further solvent(s); react. in a stream of dry N2, refluxing for 3-5 h in 1,2,4-trichlorobenzene, monitored by UV, evapn., extg. with CH2Cl2, chromy. (Al2O3 (neutral), CH2Cl2/MeOH (100:1 to 10:1)), evapn., dissolving in toluene, refluxing in 2N aq. KOH for 2-6 h; pptn. on evapn., washing with water to remove alkali, crystn. (CH2Cl2 or CHCl3), elem. anal.;

Reference yield: 73.0%

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: rhenium pentachloride

: 128709-60-4
Re(TPP)Cl₃

: 128873-09-6
methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

Guidance literature:: With methanol; sodium acetate; In methanol; chloroform; react. in a stream of dry N2, refluxing for 3-5 h in 1,2,4-trichlorobenzene, monitored by UV, evapn., extg. with CH2Cl2, chromy. (Al2O3 (neutral), CH2Cl2/MeOH (100:1 to 10:1)), evapn., dissolving in CHCl3/MeOH, addn. of MeOH/NaOAc, refuxing for 12 h; evapn., washing with water, recrystn. (CHCl3/MeOH 10:1), elem. anal.;

Reference yield: 21.0%

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: rhenium pentachloride

: 128709-60-4
Re(TPP)Cl₃

Guidance literature:: In further solvent(s); byproducts: HCl; react. in a stream of dry N2, heating a soln. of the porphyrin in 1,2,4-trichlorobenzene to 120°C for 30 min., addn. of (ReCl5)2, refluxing for 1 h, change of colour from green to brown-red; evapn., dissolving in CHCl3, chromy. (Al2O3), washing repeatedly with HCl/MeOH, chromy. (Al2O3(neutral), CHCl3), elem. anal.;