methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

Base Information

Chemical Name:methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}
CAS No.:128873-09-6
Molecular Formula:C₄₅H₃₁N₄O₂Re
Molecular Weight:845.974
Hs Code.:

Synonyms:

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Chemical Property of methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

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Technology Process of methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

There total 2 articles about methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: rhenium pentachloride

: 128709-60-4
Re(TPP)Cl₃

: 128873-09-6
methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

Guidance literature:: With methanol; sodium acetate; In methanol; chloroform; react. in a stream of dry N2, refluxing for 3-5 h in 1,2,4-trichlorobenzene, monitored by UV, evapn., extg. with CH2Cl2, chromy. (Al2O3 (neutral), CH2Cl2/MeOH (100:1 to 10:1)), evapn., dissolving in CHCl3/MeOH, addn. of MeOH/NaOAc, refuxing for 12 h; evapn., washing with water, recrystn. (CHCl3/MeOH 10:1), elem. anal.;

Reference yield:

: 67-56-1
methanol

: Oxorhenato(VII)tetraphenylporphyrinatorhenium(V)

: tetra-n-butylammonium hydroxide

: 128873-09-6
methoxo-oxo(5,10,15,20-tetraphenylporphyrinato)rhenium(V)}

Guidance literature:: With CO₂; In methanol; dichloromethane; Re-compd. and ammonium salt were dissolved in CH2Cl2/CH3OH (9:1); filtered, into filtrate CO2 bubbled for 3 min; ppt. filtered, thoroughly washed with methanol;
DOI:10.1002/(SICI)1521-3749(200004)626:4<985::AID-ZAAC985>3.0.CO;2-3