Benzene, 1-(ethenyloxy)-3-methoxy-

Base Information

• Chemical Name: Benzene, 1-(ethenyloxy)-3-methoxy-
• CAS No.: 10536-50-2
• Molecular Formula: C9H10O2
• Molecular Weight: 150.177
• Mol file: 10536-50-2.mol

Synonyms:

Chemical Property of Benzene, 1-(ethenyloxy)-3-methoxy-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1-(ethenyloxy)-3-methoxy-

There total 4 articles about Benzene, 1-(ethenyloxy)-3-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

O-methylresorcine (150-19-6) + ethylene dibromide (106-93-4) → 3-methoxyphenyl vinyl ether (10536-50-2)

Guidance literature:

O-methylresorcine; ethylene dibromide; With potassium carbonate; In acetone; for 12h; Inert atmosphere; Reflux;

With potassium tert-butylate; In tetrahydrofuran; for 0.166667h; Inert atmosphere;

DOI:10.3390/molecules25030602

Reference yield: 69.0%

C14H21NO3 → 3-methoxyphenyl vinyl ether (10536-50-2)

Guidance literature:

With N,O-bis-(trimethylsilyl)-acetamide; In toluene; for 0.5h; Reflux;

DOI:10.1016/j.tet.2021.132108

Reference yield:

1-(2-(3-methoxyphenoxy)ethyl)piperidine → 3-methoxyphenyl vinyl ether (10536-50-2)

Guidance literature:

Multi-step reaction with 2 steps

1: peracetic acid; acetic acid / dichloromethane / 0.08 h

2: N,O-bis-(trimethylsilyl)-acetamide / toluene / 0.5 h / Reflux

With peracetic acid; N,O-bis-(trimethylsilyl)-acetamide; acetic acid; In dichloromethane; toluene; 2: |Cope Elimination;

DOI:10.1016/j.tet.2021.132108

upstream raw materials:

O-methylresorcine

ethylene dibromide

Downstream raw materials:

O-methylresorcine