ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃

Base Information

• Chemical Name: ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃
• CAS No.: 180776-52-7
• Molecular Formula: CF₃O₃S*C₁₄H₁₁ClO₄Re
• Molecular Weight: 613.969
• Mol file: 180776-52-7.mol

Synonyms:

Chemical Property of ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃

There total 1 articles about ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Re(C(O)C6H2(CH3)3)(CO)5] (155941-72-3) + dichloromethane (75-09-2) + trifluoromethylsulfonic anhydride (358-23-6) → ReCl(CO)4(CC6H2(CH3)3)(1+)*O3SCF3(1-) = [ReCl(CO)4(CC6H2(CH3)3)]O3SCF3 (180776-52-7)

Guidance literature:

In dichloromethane; (N2); addn. of (CF3SO2)2O in CH2Cl2 with rapid stirring to a -40°C cold soln. of the Re complex in CH2Cl2, stirring (30 min); solvent removal, washing (toluene; light petroleum);

DOI:10.1039/DT9960002827

Reference yield: 70.0%

ReCl(CO)4(CC6H2(CH3)3)(1+)*O3SCF3(1-) = [ReCl(CO)4(CC6H2(CH3)3)]O3SCF3 (180776-52-7) + lithium perchlorate + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → ReCl(CO)2(CC6H2(CH3)3)(C26H24P2)(1+)*ClO4(1-)*2C4H8O=[ReCl(CO)2(CC6H2(CH3)3)(C26H24P2)]ClO4*2C4H8O

Guidance literature:

In tetrahydrofuran; (N2); refluxing the Re complex and the ligand in THF for 6 h, evapn. to dryness (vac.), dissoln. (MeOH), pptn. with LiClO4; chromy. (SiO2/Et2O; CHCl3); elem. anal.;

DOI:10.1039/DT9960002827

Reference yield: 50.0%

ReCl(CO)4(CC6H2(CH3)3)(1+)*O3SCF3(1-) = [ReCl(CO)4(CC6H2(CH3)3)]O3SCF3 (180776-52-7) + o-phenylenebis(diphenylphosphine) (13991-08-7) + lithium perchlorate → ReCl(CC6H2(CH3)3)(C30H24P2)2(1+)*ClO4(1-)*1.5CHCl3*0.25CH3OH=[ReCl(CC6H2(CH3)3)(C30H24P2)2]ClO4*1.5CHCl3*0.25CH3OH

Guidance literature:

In tetrahydrofuran; methanol; (N2); refluxing the Re complex and the ligand in THF for 12 h, solvent removal (vac.), dissoln. (MeOH), pptn. with LiClO4; recrystn. by diffusion of Et2O in CHCl3/MeOH soln.; elem. anal.;

DOI:10.1039/DT9960002827

upstream raw materials:

[Re(C(O)C₆H₂(CH₃)3)(CO)5]

dichloromethane

trifluoromethylsulfonic anhydride