trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

Base Information

Chemical Name:trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane
CAS No.:901764-02-1
Molecular Formula:C₃₄H₄₅Cl₃GeO₃
Molecular Weight:680.678
Hs Code.:

Synonyms:

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Chemical Property of trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

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Technology Process of trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

There total 4 articles about trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 10038-98-9
germaniumtetrachloride

: 340254-90-2
5,5',5''-tri-tert-butyl-2,2',2''-trimethoxytriphenylmethane

: 901764-02-1
trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

Guidance literature:: With n-BuLi; hexamethylphosphoramide; In 1,2-dimethoxyethane; benzene; soln. of BuLi in hexane added to soln. of triarylmethane in C6H6 at 50°C; stirred at 50°C for 12 h; solvent removed (vac.); DME and amide added; GeCl4 added at 0°C; stirred at 0°C for 2 h and at room temp. for 12 h; solvent removed; residue treated with EtOH and H2O; extd. (CHCl3); solvent removed (vac.); dissolved in ether; washed (aq. NaOH); extract combined (MgSO4); solvent removed (vac.); chromd. (silica gel, hexane/EtOAc, 15/1); elem. anal.;
DOI:10.1021/om060031o

Reference yield:

: 901764-03-2
trifluoro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

: 901764-02-1
trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane; hexane

In hexane; dichloromethane;
DOI:10.1021/om060031o

Reference yield:

: 901764-03-2
trifluoro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

: 10294-34-5
boron trichloride

: 901764-02-1
trichloro[tris(3-tert-butyl-6-methoxyphenyl)methyl]germane

Guidance literature:: In hexane; dichloromethane; soln. of BCl3 (10 equiv.) in hexane was added to soln. of Ge compd. in CH2Cl2 at 0°C; mixt. was stirred at 0°C for 3 h; treated with EtOH and H2O; extd. (CHCl3); dried (MgSO4); solvent removed(vac.); NMR monitoring;
DOI:10.1021/om060031o