(PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

Base Information

Chemical Name:(PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9
CAS No.:384345-05-5
Molecular Formula:C₄₅H₃₂O₉P₂Ru₃
Molecular Weight:1081.9
Hs Code.:

Synonyms:

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Chemical Property of (PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

Chemical Property:

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Technology Process of (PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

There total 5 articles about (PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116198-00-6,66172-60-9
{Ru3(CO)10(PPh3)2}

: 1333-74-0,12385-13-6
parahydrogen

: (triphenylphosphine)2(hydride)(μ-hydride)Ru2(carbonyl)9

: 384345-05-5,383905-99-5,383906-04-5
(PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

Guidance literature:: In ⁽²⁾H₈-toluene; 1 atm of hydrogen (enriched in the para spin state; was prepd. by cooling H2 to 77 K over a paramagnetic catalyst Fe2O3) was first introduced into an NMR tube cooled in liquid nitrogen; the mixt. was thawed immediately and warmed to 253 K; not isolated, determined by NMR; Kinetics;
DOI:10.1021/ja004245n

Reference yield:

: 116198-00-6,66172-60-9
{Ru3(CO)10(PPh3)2}

: 1333-74-0,12385-13-6
parahydrogen

: 384345-05-5,383905-99-5,383906-04-5
(PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

: [Ru₃H₂(CO)9(P(C₆H₅)3)]

: [Ru₃H(H)(CO)9(P(C₆H₅)3)2]

Guidance literature:: In benzene-d6; byproducts: CO; 296 K; not isolated, detected by NMR;
DOI:10.1002/1521-3773(20011015)40:20<3874::AID-ANIE3874>3.0.CO;2-9

Reference yield:

: 116198-00-6,66172-60-9
{Ru3(CO)10(PPh3)2}

: 1333-74-0,12385-13-6
parahydrogen

: 586-39-0,51209-60-0
1-nitro-3-vinyl-benzene

: 384345-05-5,383905-99-5,383906-04-5
(PMe2Ph)(H)Ru(μ-H)Ru(PPh3)(CO)9

: [Ru(H)2(CO)2(3-nitrostyrene)(triphenyl phosphine)]

: [Ru₃H₂(CO)9(P(C₆H₅)3)]

: [Ru₃H(H)(CO)9(P(C₆H₅)3)2]

Guidance literature:: In benzene-d6; byproducts: CO; in presence of 100-fold excess of 3-nitrostyrene; not isolated, detected by NMR;
DOI:10.1002/1521-3773(20011015)40:20<3874::AID-ANIE3874>3.0.CO;2-9