rac-cis-C₁-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

Base Information

• Chemical Name: rac-cis-C₁-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)
• CAS No.: 82442-74-8
• Molecular Formula: C₄₀H₄₀I₂P₄Ru
• Molecular Weight: 999.532
• Mol file: 82442-74-8.mol

Synonyms:

Chemical Property of rac-cis-C₁-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of rac-cis-C₁-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

There total 1 articles about rac-cis-C₁-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

rac-cis-C1-dichloro((R,R)-o-phenylenebis(methylphenylarsine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82442-78-2) + lithium iodide (10377-51-2) → rac-cis-C1-diiodobis((RR)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82442-74-8)

Guidance literature:

In tetrahydrofuran; THF soln. of Ru complex heated with 10-30 excess of LiI at reflux temp.for 3 min; solvent removed, product extd. into CH2Cl2, crystd. by addn. of ethanol;

upstream raw materials:

rac-cis-C₁-dichloro((R,R)-o-phenylenebis(methylphenylarsine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

lithium iodide