(triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct

Base Information

• Chemical Name: (triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct
• CAS No.: 383863-81-8
• Molecular Formula: CH₂Cl₂*C₂₅H₂₂AuO₃PS
• Molecular Weight: 715.387
• Mol file: 383863-81-8.mol

Synonyms:

Chemical Property of (triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct

Chemical Property:

Purity/Quality:

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Technology Process of (triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct

There total 1 articles about (triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + dichloromethane (75-09-2) + silver(I) 4-methylbenzenesulfonate (16836-95-6) → (triphenylphosphine)gold(I)-p-tolylsulfonate dichloromethane adduct (383863-81-8)

Guidance literature:

In dichloromethane; byproducts: AgCl; under dry N2; soln. of silver p-tolylsulfonate treated with soln. of (Ph3P)AuCl (20°C, 3 h, stirring); AgCl filtered off; pptd. with pentane; filtered; washed with toluene; crystd. from CH2Cl2/pentane (-30°C); elem. anal.;

DOI:10.1016/j.molcata.2003.11.011

upstream raw materials:

(triphenylphosphine)gold(I) chloride

dichloromethane

silver(I) 4-methylbenzenesulfonate