trans-{Pt(cycloheptylNH2)2Cl2}

Base Information

• Chemical Name: trans-{Pt(cycloheptylNH2)2Cl2}
• CAS No.: 176706-00-6
• Molecular Formula: C₁₄H₃₀Cl₂N₂Pt
• Molecular Weight: 492.392
• Mol file: 176706-00-6.mol

Synonyms:

Chemical Property of trans-{Pt(cycloheptylNH2)2Cl2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-{Pt(cycloheptylNH2)2Cl2}

There total 4 articles about trans-{Pt(cycloheptylNH2)2Cl2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cis-{Pt(cycloheptylNH2)2Cl2} (76647-86-4,41637-13-2,176706-00-6) → trans-{Pt(cycloheptylNH2)2Cl2} (176706-00-6,41637-13-2,76647-86-4)

Guidance literature:

In N,N-dimethyl-formamide; conversion of the cis-complex into the trans-complex in DMF during spontaneous evapn. of the solvent within two months; washing the solid trans-complex with water, methanol and diethyl ether;

DOI:10.1007/BF00819526

Reference yield: 39.0%

potassium tetrachloroplatinate(II) (10025-99-7) + cycloheptanamine (5452-35-7) → cis-{Pt(cycloheptylNH2)2Cl2} (76647-86-4,41637-13-2,176706-00-6) + trans-{Pt(cycloheptylNH2)2Cl2} (176706-00-6,41637-13-2,76647-86-4)

Guidance literature:

In water; addn. of cycloheptylamine to an aq. soln. of K2PtCl4 and stirring at room temp. for 2 h; filtering off the cis-complex obtained as main product, washing with water, methanol an diethyl ether and drying under vacuum, elem. anal.;

DOI:10.1007/BF00819526

Reference yield: 39.0%

potassium tetrachloroplatinate(II) (10025-99-7) + cycloheptanamine (5452-35-7) → cis-{Pt(cycloheptylNH2)2Cl2} (76647-86-4,41637-13-2,176706-00-6) + trans-{Pt(cycloheptylNH2)2Cl2} (176706-00-6,41637-13-2,76647-86-4)

Guidance literature:

In water; addn. of cycloheptylamine to an aq. soln. of K2PtCl4 and stirring at room temp. for 2 h; filtering off the cis-complex obtained as main product, washing with water, methanol an diethyl ether and drying under vacuum, elem. anal.;

DOI:10.1007/BF00819526

upstream raw materials:

potassium tetrachloroplatinate(II)

cycloheptanamine

potassium iodide

cis-{Pt(cycloheptylNH2)2Cl2}

Downstream raw materials:

trans-{Pt(cycloheptylNH2)2Cl2}