1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

Base Information

Chemical Name:1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane
CAS No.:1334119-82-2
Molecular Formula:C₂₂H₂₈N₂O₃S₂
Molecular Weight:432.608
Hs Code.:

Synonyms:

Suppliers and Price of 1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

There total 1 articles about 1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 870-24-6
2-chloroethanamine hydrochloride

: 90-02-8
salicylaldehyde

: 2150-02-9
bis(2-mercaptoethyl)ether

: 1334119-82-2
1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

Guidance literature:: 2-chloroethanamine hydrochloride; bis(2-mercaptoethyl)ether; With sodium; In ethanol; Inert atmosphere; Reflux;

salicylaldehyde; In ethanol; for 48h; Reflux; Inert atmosphere;
DOI:10.1139/v11-081

Reference yield: 89.0%

: nickel(II) chloride hexahydrate

: 1334119-82-2
1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

: [Ni(1,8-bis(salicylaldimine)-3,6-dithiaoctane(-1H))Cl]*H₂O

Guidance literature:: In methanol; warm (40°C) soln. of ligand in MeOH was mixed with warm (40°C) soln. of Ni(OAc)2*2H2O in MeOH; slowly evapd. in air, triturated with MeCN, filtered, washed with MeCN, dried, dissolved in MeOH, concd., filtered, filtrate was added to ether,precipitate was collected, washed with ether, elem. anal.;
DOI:10.1139/v11-081

Reference yield: 73.0%

: 67-56-1
methanol

: nickel(II) chloride hexahydrate

: 1334119-82-2
1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane

: [Ni(1,11-bis(salicylaldimine)-6-oxa-3,9-dithiaundecane)]Cl₂*CH₃OH

Guidance literature:: In methanol; warm (40°C) soln. of ligand in MeOH was mixed with warm (40°C) soln. of Ni(OAc)2*2H2O in MeOH; slowly evapd. in air, triturated with MeCN, filtered, washed with MeCN, dried, dissolved in MeOH, concd., filtered, filtrate was added to ether,precipitate was collected, washed with ether, elem. anal.;
DOI:10.1139/v11-081