Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

Base Information

• Chemical Name: Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))
• CAS No.: 507264-41-7
• Molecular Formula: C₄₃H₆₈LuN₃O₂Si
• Molecular Weight: 862.084
• Mol file: 507264-41-7.mol

Synonyms:

Chemical Property of Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

There total 2 articles about Lu(CH₂SiMe₃)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 + 2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine (184640-73-1) → Lu(CH2SiMe3)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine(2-)) (507264-41-7)

Guidance literature:

In tetrahydrofuran; soln. of Lu-complex in THF was added dropwise to stirred soln. of ligandin THF at ambient temp., stirred for 1 h under Ar; filtered, volatiles were removed in vacuo, recrystd. from hexane and toluene at -30°C; elem. anal.;

DOI:10.1021/om020783s

Reference yield:

LuCl3(THF)3 (24614-69-5,144491-06-5,120496-88-0) → Lu(CH2SiMe3)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine(2-)) (507264-41-7)

Guidance literature:

Multi-step reaction with 2 steps

1: hexane

2: tetrahydrofuran

In tetrahydrofuran; hexane;

DOI:10.1021/om020783s

Reference yield: 87.0%

Lu(CH2SiMe3)(THF)2(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine(2-)) (507264-41-7) + diethylamine (109-89-7) → LuNEt2(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine(2-)) (507264-44-0)

Guidance literature:

In hexane; ligand was added to stirred soln. of Lu-complex in hexane at ambient temp, stirred for 18 h under Ar; filtered, volatiles were removed in vacuo, recrystd. from hexane; elem. anal.;

DOI:10.1021/om020783s

upstream raw materials:

2,6-bis(2,6-bis((2,6-diisopropylphenyl)amino)methyl)pyridine

LuCl₃(THF)3

Downstream raw materials:

LuNEt₂(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))

LuN(SiMe₂)2(THF)(2,6-bis(((2,6-diisopropylphenyl)amino)methyl)pyridine^(2-))