[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]B(C₆H₃(CF₃)2)4

Base Information

• Chemical Name: [(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]B(C₆H₃(CF₃)2)4
• CAS No.: 175084-15-8
• Molecular Formula: C₂₂H₁₄F₆N₃Pd*C₃₂H₁₂BF₂₄
• Molecular Weight: 1404

Synonyms:

Chemical Property of [(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]B(C₆H₃(CF₃)2)4

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Technology Process of [(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]B(C₆H₃(CF₃)2)4

There total 1 articles about [(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[(NC₅H₃CHCHC₅H₃N)Pd(CH₃)(NCC₆H₃(CF₃)2)]B(C₆H₃(CF₃)2)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(1,10-phenanthroline)methylchloropalladium(II) + 3,5-bis(trifluoromethyl)benzonitrile (27126-93-8) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [(NC5H3CHCHC5H3N)Pd(CH3)(NCC6H3(CF3)2)](1+)*B(C6H3(CF3)2)4(1-)=[(NC5H3CHCHC5H3N)Pd(CH3)(NCC6H3(CF3)2)]B(C6H3(CF3)2)4 (175084-15-8)

Guidance literature:

In diethyl ether; byproducts: NaCl; (Ar); std. Schlenk technique; soln. of Na salt in Et2O was added to mixt. of Pd complex and nitrile in Et2O; stirred at room temp. for 30 min; volatiles removed (vac.); CH2Cl2 added; filtered; washed (CH2Cl2); washings combined with filtrate; concd. (vac.); pentane added; stirred overnight; filtered; washed (pentane); dried in vac. at room temp. for 2 h; elem. anal.;

DOI:10.1021/om061025v

Reference yield:

triethylsilane (617-86-7) + [(1,10-phenanthroline)Pd(CH3)(NC(3,5-C6H3(CF3)2)][B(3,5-C6H3(CF3)2)4] (175084-15-8) → [(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4] (388567-20-2)

Guidance literature:

In dichloromethane-d2; byproducts: CH4; in NMR tube; HSiEt3 added to soln. of Pd complex (molar ratio 1:1) in CD2Cl2 at -78°C; shaken briefly; kept at -81°C for 5 min; not isolated; monitored by (1)H NMR spectra;

DOI:10.1021/ja049806f

Reference yield:

triethylsilane (617-86-7) + [(1,10-phenanthroline)Pd(CH3)(NC(3,5-C6H3(CF3)2)][B(3,5-C6H3(CF3)2)4] (175084-15-8) + dimethyl bisallylmalonate (35357-77-8) → trans,trans-[(1,10-phenanthroline)Pd(CHCH(Me)CH(CH2SiEt3)CH2C(COOMe)(COOMe))][B(3,5-C6H3(CF3)2)4]

Guidance literature:

In dichloromethane-d2; byproducts: CH4; HSiEt3 was added to a CD2Cl2 soln. of Pd complex at -81°C, dimethyl diallylmalonate was added at -62°C, the mixt. was warmed at -41°C for 2h, the mixt. was warmed at -9°C for 2 h; each step was monitored by NMR; not isolated, detected by NMR;

DOI:10.1021/om010876u

upstream raw materials:

3,5-bis(trifluoromethyl)benzonitrile

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

[(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C₆H₃(CF₃)2))][B(3,5-C₆H₃(CF₃)2)4]

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