trans-dichlorobis(diethyl sulfide)platinum(II)

Base Information

• Chemical Name: trans-dichlorobis(diethyl sulfide)platinum(II)
• CAS No.: 20244-83-1
• Molecular Formula: C₈H₂₀Cl₂PtS₂
• Molecular Weight: 446.365
• Mol file: 20244-83-1.mol

Synonyms:

Chemical Property of trans-dichlorobis(diethyl sulfide)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dichlorobis(diethyl sulfide)platinum(II)

There total 27 articles about trans-dichlorobis(diethyl sulfide)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield:

{Pt2} (148832-26-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6)

Guidance literature:

Multi-step reaction with 3 steps

1: water

2: water

3: hydrogenchloride

In hydrogenchloride; water;

DOI:10.1039/JR9300000349

upstream raw materials:

trans-dichlorobis(diethyl sulfide)platinum(II)

diethyl sulphide

potassium tetrachloroplatinate(II)

hydrogenchloride

Downstream raw materials:

{PtBr2}

trans-dichlorobis(diethyl sulfide)platinum(II)

{Ptaes₂Cl₄}

dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)