NbCl₄{NP(C₆H₅)3}(CH₃CN)

Base Information

Chemical Name:NbCl₄{NP(C₆H₅)3}(CH₃CN)
CAS No.:137864-99-4
Molecular Formula:C₂₀H₁₈Cl₄N₂NbP
Molecular Weight:552.068
Hs Code.:

NbCl<sub>4</sub>{NP(C<sub>6</sub>H<sub>5</sub>)3}(CH<sub>3</sub>CN)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of NbCl₄{NP(C₆H₅)3}(CH₃CN)

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Technology Process of NbCl₄{NP(C₆H₅)3}(CH₃CN)

There total 1 articles about NbCl₄{NP(C₆H₅)3}(CH₃CN) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.2%

: 13892-06-3
N-trimethylsilyl(triphenylphosphoranylidene)amine

: 10026-12-7
niobium pentachloride

: 137864-99-4
(triphenylphosphaneiminato)niobiumCl₄*CH₃CN

Guidance literature:: With acetonitrile; In acetonitrile; byproducts: (CH3)3SiCl; Dropwise addn. of a soln. of organic compound (with stirring) to a soln. of NbCl5.; distn. after 1 h, cooling, filtn., washing (cold acetonitrile), drying in vac., elem. anal.;

Reference yield: 24.9%

: 33100-27-5
15-crown-5

: 137864-99-4
(triphenylphosphaneiminato)niobiumCl₄*CH₃CN

: 7681-49-4
sodium fluoride

: 137885-79-1
{sodium-15-crown-5}{pentafluorotriphenylphosphaneiminatoniobium}

Guidance literature:: In acetonitrile; byproducts: NaCl; Addn. of NaF and 15-crown-5 to a soln. of Nb-compound with stirring at room temperature, stirring for 5 d at room temperature.; filtration, concn. in vac., filtration, washing (cold acetonitrile), drying in vac., elem. anal.;

Reference yield:

: 33100-27-5
15-crown-5

: 137864-99-4
NbCl₄{NP(C₆H₅)3}(CH₃CN)

: 7681-49-4
sodium fluoride

: 143155-58-2
{PPh₃NH₂}{pentafluoro(triphenylphosphaniminato)niobium}

Guidance literature:: With H₂O; In acetonitrile; byproducts: {Na(15-crown-5)}{NbOF4}; a mixt. of the Nb complex, 15-crown-5, NaF, and a stoich. amt. of H2O was refluxed in CH3CN for several days;; cooling; filtration; concn. of filtrate; crystn. on standing at room temp.; the crystals were filtered off, washed with a small amt. of cold CH3CN, and dried under vac.; elem. anal.;;
DOI:10.1016/0925-8388(92)90728-R