{[PhBP₃^Ph]Fe}(CO)₂

Base Information

• Chemical Name: {[PhBP₃^Ph]Fe}(CO)₂
• CAS No.: 494843-67-3
• Molecular Formula: C₄₇H₄₁BFeO₂P₃
• Molecular Weight: 797.421
• Mol file: 494843-67-3.mol

Synonyms:

Chemical Property of {[PhBP₃^Ph]Fe}(CO)₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {[PhBP₃^Ph]Fe}(CO)₂

There total 5 articles about {[PhBP₃^Ph]Fe}(CO)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(PhB(CH2PPh2)3)FeN(p-tolyl)] + carbon monoxide (201230-82-2) → {[PhBP3Ph]Fe}(CO)2 (494843-67-3)

Guidance literature:

In not given; byproducts: CH3C6H4NCO; at room temp.;

DOI:10.1021/ja028448i

Reference yield:

[PhB(CH2PPh2)3]Fe(PPh3) + carbon monoxide (201230-82-2) → {[PhBP3Ph]Fe}(CO)2 (494843-67-3)

Guidance literature:

In not given; treatment of (PhBP(CH2PPh2)3)Fe(PPh3) with excess CO;

DOI:10.1021/ja028448i

Reference yield:

[[PhB(CH2PPh2)3Fe]2(μ-N)][Na(THF)5] + carbon monoxide (201230-82-2) → {[PhBP3Ph]Fe}(CO)2 (494843-67-3) + PhB(CH2PPh2)3Fe(CO)2(isocyanate) (847654-77-7)

Guidance literature:

In tetrahydrofuran; under N2 atm.; Fe nitride complex was dissolved in THF in NMR tube; soln. was frozen; N2 atm. was evacuated and replaced with 1 atm. of CO; NMR tube was shaken over 10 min; volatiles removed (vac.); not isolated; monitored by NMR and IR spectroscopy;

DOI:10.1021/ja0453073

upstream raw materials:

carbon monoxide

[PhB(CH₂PPh₂)₃]FeCl

carbon dioxide