[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

Base Information

Chemical Name:[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]
CAS No.:1009104-94-2
Molecular Formula:C₃₄H₃₁I₂OP₂Rh
Molecular Weight:874.282
Hs Code.:

[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I<sub>2</sub>]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

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Technology Process of [Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

There total 2 articles about [Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.5%

: 79-20-9
acetic acid methyl ester

: 1009104-91-9
[Rh(bis(diphenylphosphino)xylene)(CO)Cl]2

: 74-88-4
methyl iodide

: 1009104-94-2
[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

Guidance literature:: In acetic acid methyl ester; other Radiation; under N2; methyl acetate and MeI added to Biotage microwave vial contg. Rh complex; heated at 140°C for 10 min; crystd. by slow evapn.; elem. anal.;
DOI:10.1039/b712974b

Reference yield:

: di(rhodium)tetracarbonyl dichloride

: 201230-82-2
carbon monoxide

: 62144-65-4
1,2-bis((diphenylphosphino)methyl)benzene

: 74-88-4
methyl iodide

: 1009104-94-2
[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

Guidance literature:: With H₂; In methanol; water; High Pressure; MeOH, H2O, Rh complex and diphosphine added to autoclave under CO-H2; sealed; pressurised with CO (5 bar); heated to 100°C with stirring;MeI added; pressurised with CO-H2 (27 bar); heated to 140-150°C; cooled; ppt. analysed;
DOI:10.1039/b712974b

Reference yield:

: 1009104-94-2
[Rh(bis(diphenylphosphino)xylene)(C(O)Me)I₂]

: [Rh(bis(diphenylphosphino)xylene)(CO))I]

Guidance literature:: With H₂; In methanol; High Pressure; under N2; Rh complex in MeOH heated at 80°C under H2 (7 bar); not isolated; detd. by (31)P NMR and IR spectra; equil. mixt. of initialand resultant Rh complexes obtained;
DOI:10.1039/b712974b