[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)]

Base Information

• Chemical Name: [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)]
• CAS No.: 1035351-53-1
• Molecular Formula: C₁₄H₂₆P₂Pt
• Molecular Weight: 451.388
• Mol file: 1035351-53-1.mol

Synonyms:

Chemical Property of [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)]

There total 1 articles about [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1,2-bis(dimethylphosphanyl)ethane (23936-60-9) + [PtMe(p-tolyl)(1,5-cyclooctadiene)] (66485-00-5) → [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)] (1035351-53-1)

Guidance literature:

In benzene; (Ar); std. Schlenk technique; P ligand was added to stirred soln. of Pt complex in C6H6; stirred at room temp. for 1.5 h; solvent removed (vac.); recrystd. (hot hexane); elem. anal.;

DOI:10.1021/om800122k

Reference yield: 24.0%

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)] (1035351-53-1) + (2-(trimethylsilyl)ethynyl)(phenyl)iodonium trifluoromethanesulfonate + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → [PtIMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe3)]

Guidance literature:

In acetone; (Ar); std. Schlenk technique; soln. of Si compd. in acetone was added tosoln. of Pt complex in acetone at -50°C; stirred at -50°C for 30 min; NaI was added; stirred at -50°C for 1 h; warmed to r oom temp.; stirred for 16 h; solvent removed (vac.); CH2Cl2 added; filtered through Celite/cotton; pentane added; left at -20°C for 30 min; filtered; washed (pentane); dried in air; elem. anal.;

DOI:10.1021/om800122k

Reference yield:

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)] (1035351-53-1) → [PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe3)(MeCN)](OTf) (1035351-66-6)

Guidance literature:

Multi-step reaction with 2 steps

1: [⁽²⁾H₆]acetone

2: acetonitrile; [⁽²⁾H₆]acetone

In [⁽²⁾H₆]acetone; acetonitrile;

DOI:10.1021/om800122k

upstream raw materials:

1,2-bis(dimethylphosphanyl)ethane

[PtMe(p-tolyl)(1,5-cyclooctadiene)]

Downstream raw materials:

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe₃)(OTf)]

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe₃)(acetone)](OTf)

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe₃)(MeCN)](OTf)

[PtMe(p-tolyl)(1,2-bis(dimethylphosphino)methane)(CCSiMe₃)(MeCN)](OTf)