cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

Base Information

• Chemical Name: cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)
• CAS No.: 92471-71-1
• Molecular Formula: C₄₀H₄₀Cl₂N₂P₂Pt
• Molecular Weight: 876.705
• Mol file: 92471-71-1.mol

Synonyms:

Chemical Property of cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

There total 3 articles about cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.5%

trans-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) (92451-52-0,92471-71-1) → cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) (92471-71-1,92451-52-0)

Guidance literature:

In dichloromethane; stirring for 24 h at room temp.; evapn. to satd. soln., layered with petroleum ether, standing for 3 d at -24°C; elem. anal.;

Reference yield: 73.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 4-(N,N-Dimethylamino)triphenylphosphine (739-58-2) → trans-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) (92451-52-0,92471-71-1)

Guidance literature:

In xylene; addn. of finelly grinded K2(PtCl4) to soln. of phosphane derivative; refluxing of suspension for 25 h under N2;; filtering, washing with ethanol/water (1:1), drying in desiccator above silica gel; elem. anal.;

Reference yield: 20.0%

cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) (92471-71-1,92451-52-0) → trans-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II) (92451-52-0,92471-71-1)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); irradn. of soln. at room temp. for 40 h; filtering, washing with benzene; elem. anal.;

upstream raw materials:

potassium tetrachloroplatinate(II)

4-(N,N-Dimethylamino)triphenylphosphine

cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

trans-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

Downstream raw materials:

cis-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)

trans-dichlorobis{(4-(dimethylamino)phenyl)diphenylphosphane}platinum(II)