Technology Process of tetrakis-(3,4,5-trichlorophenyl)stannane
There total 1 articles about tetrakis-(3,4,5-trichlorophenyl)stannane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
diethyl ether; benzene;
Ar atmosphere; addn. of SnCl4 in benzene to Cl3C6H2MgBr in ether (stirring and cooling (water bath)), refluxing (6 h), addn. of aq. HCl; filtration off, washing (ether), recrystn. (DMF); elem. anal.;
DOI:10.1007/BF00949765
- Guidance literature:
-
With
bromine; N,N-dimethyl-formamide;
In
N,N-dimethyl-formamide;
addn. og soln. of Br2 in DMF to boiling soln. of Sn-compound, cooling; removal of solvent (vac.), treatment with petroleum, filtration off; elem. anal.;
DOI:10.1007/BF00949810
- Guidance literature:
-
In
neat (no solvent);
heating (sealed ampule, 270°C, 7 h) cooling to 20°C; standing (overnight), extn. (ether), filtration, removal of solvent (vac.), recrytsn. (octane); elem. anal.;
DOI:10.1007/BF00950662
