diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate

Base Information

• Chemical Name: diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate
• CAS No.: 1256814-33-1
• Molecular Formula: C₁₂H₂₂NO₄PSn
• Molecular Weight: 393.995
• Mol file: 1256814-33-1.mol

Synonyms:

Chemical Property of diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate

There total 3 articles about diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl 2-chloropyridin-3-yl phosphate (53682-85-2) + trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) → 2,3-bis(trimethylstannyl)pyridine (83674-65-1) + diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate (1256814-33-1) + 3-(trimethylstannyl)pyridine (59020-09-6) + 2-trimethylstannylpyridine (13737-05-8)

Guidance literature:

With C₆H₄(NO₂)2; In ammonia; byproducts: C5H4N(OPO(OCH2CH3)2); NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv. and p-dinitrobenzene, stirring for 30 min; quenching, GC/MS anal.;

DOI:10.1016/j.jorganchem.2010.08.032

Reference yield:

diethyl 2-chloropyridin-3-yl phosphate (53682-85-2) + trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) → 2,3-bis(trimethylstannyl)pyridine (83674-65-1) + diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate (1256814-33-1) + 2-trimethylstannylpyridine (13737-05-8)

Guidance literature:

In ammonia; NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of 2.2 equiv. of sodium to soln. of 1 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv. and p-dinitrobenzene, stirring with irradiation for 30 min; quenching, GC/MS anal.;

DOI:10.1016/j.jorganchem.2010.08.032

Reference yield:

2,3-bis[(diethoxyphosphoryl)oxy]pyridine (1256814-29-5) + trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) → 2,3-bis(trimethylstannyl)pyridine (83674-65-1) + diethyl 2-(trimethylstannyl)pyridin-3-yl phosphate (1256814-33-1) + diethyl 3-(trimethylstannyl)pyridin-2-yl phosphate (1256814-34-2) + 3-(trimethylstannyl)pyridine (59020-09-6) + 2-trimethylstannylpyridine (13737-05-8)

Guidance literature:

In ammonia; NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirringfor 180 min in dark; quenching, GC/MS anal.;

DOI:10.1016/j.jorganchem.2010.08.032

upstream raw materials:

diethyl 2-chloropyridin-3-yl phosphate

trimethyltin(IV)chloride

sodium

2,3-bis[(diethoxyphosphoryl)oxy]pyridine

Refernces