ClCo(III)TPP(py)

Base Information

• Chemical Name: ClCo(III)TPP(py)
• CAS No.: 57384-22-2
• Molecular Formula: C₄₉H₃₃ClCoN₅
• Molecular Weight: 786.281
• Mol file: 57384-22-2.mol

Synonyms:

Chemical Property of ClCo(III)TPP(py)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ClCo(III)TPP(py)

There total 2 articles about ClCo(III)TPP(py) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aquachloro(meso-tetraphenylporphyrinato)cobalt(III) (80420-32-2) → ClCo(III)TPP(py) (57384-22-2,78694-28-7)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / pyridine; benzene

2: dichloromethane; benzene

With pyridine; In pyridine; dichloromethane; benzene;

DOI:10.1246/bcsj.54.3425

Reference yield:

[Co(TPP)(py)2]Cl (78694-29-8) → ClCo(III)TPP(py) (57384-22-2,78694-28-7)

Guidance literature:

In dichloromethane; benzene; recrystn. from benzene/CH2Cl2; elem. anal.;

DOI:10.1246/bcsj.54.3425

Reference yield: 69.0%

ClCo(III)TPP(py) (57384-22-2,78694-28-7) + (4-chlorphenyl)magnesium bromide (873-77-8) → [(tetraphenylporphyrinato)(p-Cl-phenyl)cobalt(III)] (98150-46-0)

Guidance literature:

With ammonium chloride; In diethyl ether; dichloromethane; addn. of the Grignard-compd. in ether to a stirred soln. of the complexin CH2Cl2 at 25°C, after 5 min addn. of aq. NH4Cl; the organic phase is sepd., washed, dried, evapd., the residue is dissolved in toluene, filtn., crystd., elem. anal.;

upstream raw materials:

[Co(TPP)(py)2]Cl

aquachloro(meso-tetraphenylporphyrinato)cobalt(III)

Downstream raw materials:

cobalt(II) 5,10,15,20-tetraphenylporphyrin

5,10,15,20-tetraphenyl-21H,23H-porphinecobalt(II) pyridine

[5,10,15,20-tetraphenylporphyrin]cobalt(III) chloride

nitrosyl(5,10,15,20-tetraphenylporphyrinato)(pyridine)cobalt(III)