(η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

Base Information

Chemical Name:(η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)
CAS No.:561297-18-5
Molecular Formula:C₃₇H₃₅N₃O₄P₂Ru
Molecular Weight:748.72
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

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Technology Process of (η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

There total 1 articles about (η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 252930-76-0
(η(5)-cyclopentadienyl)Ru(η(2)-1,2-bis(diphenylphosphino)ethane)(azido)

: 624-49-7
dimethylfumarate

: 561297-18-5
(η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

Guidance literature:: In dichloromethane; under N2; dimethyl fumarate (5 equiv.) and CH2Cl2 added to Ru complex; stirred at room temp. for 24 h; solvent reduced under vac.; n-hexane added; filtered; ppt. washed with n-hexane; dried under vac.; elem. anal.;
DOI:10.1021/om030079r

Reference yield: 98.0%

: 561297-18-5
(η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

: 1765-40-8
(bromomethyl)pentafluorobenzene

: (η5-C5H5)(1,2-bis(diphenylphosphino)ethane)ruthenium(Br)

Guidance literature:: In dichloromethane; byproducts: N3(CH2C6F5)C2(CO2Me)2; under N2; CH2Cl2 added to Ru complex and BrCH2C6F5 (molar ratio 1:5), stirred at 40°C for 48 h; at 50°C and 20-fold excess of BrCH2C6F5 react. completed in 1 d; solvent removed under vac.; cold n-pentane added; filtered; ppt. washed with n-pentane; dried under vac.; elem. anal.;
DOI:10.1021/om030079r

Reference yield:

: 561297-18-5
(η5-cyclopentadienyl)(dppe)Ru((N2)-4,5-bis(methoxycarbonyl)-1,2,3-triazolato)

: 100-39-0
benzyl bromide

: (η5-C5H5)(1,2-bis(diphenylphosphino)ethane)ruthenium(Br)

Guidance literature:: In dichloromethane; byproducts: N3(CH2Ph)C2(CO2Me)2; under N2; CH2Cl2 added to Ru complex and BrCH2Ph (molar ratio 1:5), stirred at 40°C for 48 h; solvent removed under vac.; cold n-pentane added; filtered; ppt. washed with n-pentane; dried under vac.;
DOI:10.1021/om030079r