(Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

Base Information

Chemical Name:(Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)
CAS No.:82532-28-3
Molecular Formula:C₄₈H₂₄O₂₂P₂Ru₆
Molecular Weight:1621.07
Hs Code.:

(Ru<sub>3</sub>(CO)11)2(1,2-bis(diphenylphosphino)ethane)

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Chemical Property of (Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

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Technology Process of (Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

There total 2 articles about (Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 82532-28-3
(Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

Guidance literature:: With C₂H₄(P(C₆H₅)2)2; Ph₂CO^(1-); In tetrahydrofuran; (N2); complex and ligand (1/0.5 molar ratio) in THF at 40°C treated dropwise with Ph2CO(1-); solvent removed, residue dissolved in C6H6, EtOH added, cooled; elem. anal.;
DOI:10.1016/S0022-328X(00)85723-X

Reference yield: 43.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 82532-28-3
(Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

Guidance literature:: With catalyst: sodium diphenylketyl; In tetrahydrofuran; mixt. of Ru-complex and ligand (molar ratio 1:0.5) dissolved in THF, treated dropwise with soln. of sodium diphenylketyl in THF; extd., crystd.; monitored by IR spectra, satisfactory elem. anal., IR and (1)H NMR spectra;
DOI:10.1039/c39820000442

Reference yield: 10.0%

: 82532-28-3
(Ru₃(CO)11)2(1,2-bis(diphenylphosphino)ethane)

: 34438-91-0,1149341-24-1,1149341-22-9,1149341-27-4,1149341-23-0
[Ru4(μ-H)4(CO)12]

: 1,2-H₄Ru₄(CO)10(dppe)

: {Ru₃H(CO)9((C₆H₅)PCH₂CH₂P(C₆H₅)2)}

: [Ru₄H₄(CO)11]2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Guidance literature:: With H₂; In cyclohexane; High Pressure; hydrogenated in an autoclave for 10 h at 80°C, at p(H2) 20 atm; evapd., preparative TLC, recrystd. from CH2Cl2/MeOH, identified by IR and elem. anal.;
DOI:10.1016/0022-328X(86)82088-5