(η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl

Base Information

Chemical Name:(η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl
CAS No.:73752-25-7
Molecular Formula:C₂₀H₁₈MnO₂P
Molecular Weight:376.273
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl

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Technology Process of (η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl

There total 1 articles about (η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 12079-65-1
cymantrene

: 72553-94-7
4,5-dimethyl-2-phenylphosphinidine

: 73752-25-7
(η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl

Guidance literature:: With C₄H₈O; In tetrahydrofuran; Irradiation (UV/VIS); (Ar); soln. of Mn complex was irradiated for 1 h at room temp., then phosphorinederiv. was added and mixt. stirred for 1 h; solvent was evapd. and residue chromd. (silica gel, hexane/benzene 80/20); recrystn. from pentane; elem. anal.;
DOI:10.1016/S0022-328X(00)81796-9

Reference yield:

: 73752-25-7
(η5-cyclopentadienyl)[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganesedicarbonyl

: 73752-28-0
(η5-cyclopentadienyl)[η6-1-6(4,5-dimethyl-2-phenylphosphorine)]manganese

: 73752-29-1
(η5-cyclopentadienyl)bis[η2-1,1(4,5-dimethyl-2-phenylphosphorine)]manganese

Guidance literature:: In cyclohexane; Irradiation (UV/VIS); (Ar); soln. of Mn complex was irradiated for 2 h; filtered soln. was evapd. in vac. at 20°C, residue was chromd. (silica gel, hexane/benzene 80/20); 1st eluate contained ligand and CpMnPC5H2MePh ((1)H-NMR), 2nd was evapd. to dryness and gave CpMnCO-complex, identified by MAS;
DOI:10.1016/S0022-328X(00)81796-9