(bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾

Base Information

Chemical Name:(bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾
CAS No.:84330-41-6
Molecular Formula:C₃₇H₃₁As₂O₁₂PRu₃
Molecular Weight:1151.67
Hs Code.:

(bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium<sup>(0)</sup>

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Chemical Property of (bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾

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Technology Process of (bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾

There total 2 articles about (bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: Ru₃(CO)10((C₆H₅)2AsCH₂As(C₆H₅)2)*C₆H₅CH₃

: 121-45-9
phosphorous acid trimethyl ester

: 84330-41-6
(bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾

Guidance literature:: With sodium diphenylketyl; In tetrahydrofuran; a THF soln. of Ph2CONa was added dropwise under N2 to a soln. of Ru3(CO)10(dpam) and P(OMe)3 in ca. 1:1.5 molar ratio in THF at 42°C, stirred for 30 min, reaction was monitored by IR spectroscopy; solvent was removed, residue recrystd. from benzene/EtOH; elem. anal.;
DOI:10.1016/0022-328X(83)85174-2

Reference yield: 28.5%

: 130144-44-4,84330-43-8
1,2-μ-{bis(diphenylarsino)methane-As,As'}-1,1,1,2,2,2,3,3,3,3-decacarbonyl-triangulo-triruthenium(0)

: 121-45-9
phosphorous acid trimethyl ester

: 84330-41-6
(bis(diphenylarsino)methane)nonacarbonyl(trimethylphosphite)ruthenium⁽⁰⁾

Guidance literature:: With diphenylketyl radical anion initiator; In tetrahydrofuran; N2-atmosphere; stirring (30 min); evapn. (vac.), chromy. (SiO2); elem. anal.;
DOI:10.1016/s0277-5387(97)00406-3