[Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4

Base Information

• Chemical Name: [Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4
• CAS No.: 1211431-76-3
• Molecular Formula: BF₄*C₃₄H₃₈ClF₃N₃OP₂Ru
• Molecular Weight: 846.966
• Mol file: 1211431-76-3.mol

Synonyms:

Chemical Property of [Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4

There total 1 articles about [Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

ammonium tetrafluroborate (13826-83-0) + [Ru(η6-4-phenyl-2-butanol)Cl2(P(p-C6H4F)3)] (1211431-54-7) + (1,3,5-triaza-7-phosphaadamantane) (53597-69-6) → [Ru(η6-4-phenyl-2-butanol)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)Cl(P(p-C6H4F)3)]BF4 (1211431-76-3,1213241-57-6)

Guidance literature:

In methanol; using standard Schlenk techniques; NH4BF4 added to MeOH soln. of Ru complex; stirred for 1 h; MeOH soln. of ligand added dropwise over 30 min; stirred for 2 h; solvent vol. reduced in vac.; pptd. with hexane; filtered; ppt. washed with hexane; recrystd. from fluorobenzene and hexane; mixt. of two diastereoisomers obtained;

DOI:10.1021/ic9020433

upstream raw materials:

ammonium tetrafluroborate

[Ru(η6-4-phenyl-2-butanol)Cl2(P(p-C6H4F)3)]

(1,3,5-triaza-7-phosphaadamantane)