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1,3,5-Triaza-7-phosphaadamantane (PTA), with a purity of at least 97%, is a versatile and water-soluble ligand used in the synthesis of metal complexes, particularly in the development of azido- and tetrazolato-platinum(II) compounds. Its incorporation facilitates environmentally friendly and efficient reactions, such as [2 + 3] cycloadditions with organonitriles, enabling the production of high-purity 5-substituted tetrazoles. PTA's water solubility simplifies purification by allowing easy separation of byproducts, making it a valuable tool in metal-mediated syntheses of nitrogen-containing heterocycles for pharmaceutical and materials applications.

53597-69-6

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53597-69-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 53597-69-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,3,5,9 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 53597-69:
(7*5)+(6*3)+(5*5)+(4*9)+(3*7)+(2*6)+(1*9)=156
156 % 10 = 6
So 53597-69-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2

53597-69-6 Well-known Company Product Price

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  • Alfa Aesar

  • (H66785)  1,3,5-Triaza-7-phosphaadamantane, 97+%   

  • 53597-69-6

  • 1g

  • 801.0CNY

  • Detail

  • Alfa Aesar

  • (H66785)  1,3,5-Triaza-7-phosphaadamantane, 97+%   

  • 53597-69-6

  • 5g

  • 3629.0CNY

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  • Aldrich

  • (695467)  1,3,5-Triaza-7-phosphaadamantane  97%

  • 53597-69-6

  • 695467-500MG

  • 435.24CNY

  • Detail

  • Aldrich

  • (695467)  1,3,5-Triaza-7-phosphaadamantane  97%

  • 53597-69-6

  • 695467-2G

  • 1,620.45CNY

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53597-69-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,3,5-Triaza-7-phosphaadamantane

1.2 Other means of identification

Product number -
Other names 1,5-Triaza-9-phospha-adamantane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:53597-69-6 SDS

53597-69-6Relevant academic research and scientific papers

Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)

Bola?o, Sandra,Albinati, Alberto,Bravo, Jorge,Gonsalvi, Luca,Peruzzini, Maurizio

, p. 360 - 363 (2008/10/09)

Boronation of the water soluble phosphine PTA (PTA = l,3,5-triaza-7- phosphaadamantane) in dry THF easily affords the N-boronated adduct N-B-PTABH3 which represents the first N-coordinated adduct of this popular water soluble phosphine (N-B-PTABH3 = 1-boranyl-1,3,5-triaza- 7-phosphaadamantane). In situ 31P NMR spectroscopy suggests the occurrence of a stepwise boronation resulting in the addition of as many as four equivalents of BH3 to PTA to give the polyboranyl species N x, Py-B-PTA(BH3)(x+y) (x = 1-3, y = 0, 1). Hydrolysis of the monoboranyl adduct occurs slowly in the presence of water yielding back PTA and boric acid, H3BO3.

REACTIVITE DE QUELQUES PHOSPHOR(III)ADAMANTANES ET DE QUELQUES ANALOGUES TRICYCLIQUES

Navech, Jacques,Kraemer, Raymond,Majoral, Jean-Pierre

, p. 1449 - 1452 (2007/10/02)

The reactivity of some phosphor(III)adamantans has been investigated.New ways of obtention of P(V)derivatives are described.

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