((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl₂

Base Information

• Chemical Name: ((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl₂
• CAS No.: 212612-42-5
• Molecular Formula: C₂₉H₄₃AlCl₂N₂
• Molecular Weight: 517.561
• Mol file: 212612-42-5.mol

Synonyms:

Chemical Property of ((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl₂

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of ((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl₂

There total 1 articles about ((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

aluminium trichloride (7446-70-0) + N,N'-bis(2,6-diisopropylphenyl)carbodiimide (2162-74-5) + tert.-butyl lithium (594-19-4) → ((t)BuC(N-(2,6-diisopropylphenyl))2)AlCl2 (212612-42-5)

Guidance literature:

In diethyl ether; hexane; byproducts: LiCl; N2-atmosphere; addn. of soln. of (t)BuLi (hexanes) to soln. of carbodiimide at 0°C, stirring at room temp. for 2 h, cooling to -78°C, addn. of soln. of 1 equiv. of AlCl3, stirring for 18 h at room temp.; evapn., extn. (pentane), crystn. at -30°C; elem. anal.;

DOI:10.1021/om9802358

upstream raw materials:

aluminium trichloride

N,N'-bis(2,6-diisopropylphenyl)carbodiimide

tert.-butyl lithium

Refernces