trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]

Base Information

Chemical Name:trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]
CAS No.:352027-38-4
Molecular Formula:C₄₅H₃₇IO₂P₂Pd
Molecular Weight:905.06
Hs Code.:

trans-[Pd(C<sub>6</sub>H<sub>4</sub>(OC(O)CHCH<sub>2</sub>)-2)I(triphenylphosphine)2]

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]

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Technology Process of trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]

There total 1 articles about trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 67264-21-5
2-iodophenyl acrylate

: 603-35-0
triphenylphosphine

: 32005-36-0
bis(dibenzylideneacetone)-palladium⁽⁰⁾

: 352027-38-4
trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]

Guidance literature:: In toluene; comps. were mixed in dry degassed toluene and stirred for 4 h; evapd., the residue was extd. with CH2Cl2, the org. exts. were filtered over anhyd. MgSO4, the soln. was concd., the residue was chromd. (SiO2, (C2H5)2O/hexane), the solid was recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/om010074z

Reference yield: 91.3%

: 366-18-7
[2,2]bipyridinyl

: 352027-38-4
trans-[Pd(C₆H₄(OC(O)CHCH₂)-2)I(triphenylphosphine)2]

: 73491-36-8
thallium(I) triflate

: 352027-42-0
[Pd(C₆H₄(OC(O)CHCH₂)-2)(2,2'-bipyridine)(triphenylphosphine)](O₃SCF₃)

Guidance literature:: In dichloromethane; Pd complex was added to a suspn. of TlOSO2CF3 in CH2Cl2, 2-3 min later bipyridine was added to the mixt., the mixt. was stirred for 14 h; the suspn. was filtered over Celite, the filtrate was concd., the foam was stirred with (C2H5)2O for 1 h, (C2H5)2O was decanted, the solid was dried in vac.; elem. anal.;
DOI:10.1021/om010074z