cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV)

Base Information

• Chemical Name: cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV)
• CAS No.: 170471-29-1
• Molecular Formula: C₂₀H₂₆Cl₄N₂O₂Si₂Ti
• Molecular Weight: 572.302
• Mol file: 170471-29-1.mol

Synonyms:

Chemical Property of cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV)

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV)

There total 1 articles about cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

titanium tetrachloride (7550-45-0) + 2-(trimethylsilyloxy)phenyl isocyanide (86149-22-6) → cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV) (170471-29-1)

Guidance literature:

In hexane; Ar-atmosphere; pptn. on dropwise addn. of TiCl4 to 2 equiv. ligand at -10°C (over 10 min), stirring for 10 min; collection (filtration), washing (hexane), recrystn. (PhMe/hexane), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(95)05709-X

upstream raw materials:

titanium tetrachloride

2-(trimethylsilyloxy)phenyl isocyanide