bis(triphenylphosphine)gold(I) triflate

Base Information

• Chemical Name: bis(triphenylphosphine)gold(I) triflate
• CAS No.: 61359-40-8
• Molecular Formula: CF₃O₃S*C₃₆H₃₀AuP₂
• Molecular Weight: 870.619
• Mol file: 61359-40-8.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)gold(I) triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(triphenylphosphine)gold(I) triflate

There total 10 articles about bis(triphenylphosphine)gold(I) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris[(triphenylphosphine)gold(I)]oxonium trifluoromethanesulfonate (188422-36-8) → bis(triphenylphosphine)gold(I) triflate (61359-40-8,147141-54-6) + gold (7440-57-5,457905-15-6)

Guidance literature:

In acetonitrile; byproducts: (C6H5)3PO; soln. refluxed under Ar in the presence of poly(N-vinylpyrrolidone) for 2 h; Au nanoparticles; detn. by UV and 31P NMR;

DOI:10.1039/b111679g

Reference yield:

triphenylphosphinegold(I) triflate (156397-47-6) → bis(triphenylphosphine)gold(I) triflate (61359-40-8,147141-54-6) + gold (7440-57-5,457905-15-6)

Guidance literature:

With C₆H₁₃CCH; In chloroform-d1; keeping soln. of gold compd. and acetylene deriv. in CDCl3 at room temp.; Kinetics;

DOI:10.1021/ja3011397

Reference yield:

trifluoromethanesulfonyloxy(triphenylphosphine)gold(I) (156397-47-6) + triphenylphosphine (603-35-0) → Au+(Ph3P)2OTf (147141-54-6,61359-40-8)

Guidance literature:

In dichloromethane; at 20 ℃;

DOI:10.1002/chem.201304271

upstream raw materials:

tris[(triphenylphosphine)gold(I)]oxonium trifluoromethanesulfonate

(triphenylphosphine)gold(I) chloride

[W(.tplbond.CN(Et)Me)(CO)2(η(5)-C5H5)]

silver trifluoromethanesulfonate

Downstream raw materials:

[Au₂(phenylacetylide)(triphenylphosphine)3]OTf

Refernces

• 1、 Wang, Weibo,Hammond, Gerald B.,Xu, Bo. "Ligand effects and ligand design in homogeneous gold(I) catalysis". . p. 5697 - 5705. Retrieved 2012/06/04.
• 2、 Gabrielli, William F.,Nogai, Stefan D.,McKenzie, Jean M.,Cronje, Stephanie,Raubenheimer, Helgard G.. "Tetrazolyl and tetrazolylidene complexes of gold: A synthetic and structural study". . p. 2208 - 2218. Retrieved 2011/04/23.