C₄₀H₅₆O₁₀

Base Information

• Chemical Name: C₄₀H₅₆O₁₀
• CAS No.: 854749-37-4
• Molecular Formula: C₄₀H₅₆O₁₀
• Molecular Weight: 696.879
• Mol file: 854749-37-4.mol

Synonyms:

Chemical Property of C₄₀H₅₆O₁₀

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₀H₅₆O₁₀

There total 12 articles about C₄₀H₅₆O₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-5-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)pentanal (854749-30-7) → C40H56O10 (854749-37-4)

Guidance literature:

Multi-step reaction with 8 steps

1: 100 percent / MgBr₂*Et₂O / -78 °C

2: 80 percent / trimethylsilyl triflate / diethyl ether / -78 °C

3: mCPBA

4: tetra-n-butylammonium fluoride

5: tetrapropylammonium perruthanate; N-methylmorpholine N-oxide

6: 80 percent / DDQ / H₂O; CH₂Cl₂

With tetrapropylammonium perruthennate; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; magnesium bromide; In diethyl ether; dichloromethane; water; 6: Pinnick oxidation;

DOI:10.1021/ol050512o

Reference yield:

(4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-2-trimethylsilanylmethyl-oct-1-en-4-ol (854749-31-8) → C40H56O10 (854749-37-4)

Guidance literature:

Multi-step reaction with 7 steps

1: 80 percent / trimethylsilyl triflate / diethyl ether / -78 °C

2: mCPBA

3: tetra-n-butylammonium fluoride

4: tetrapropylammonium perruthanate; N-methylmorpholine N-oxide

5: 80 percent / DDQ / H₂O; CH₂Cl₂

With tetrapropylammonium perruthennate; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane; water; 5: Pinnick oxidation;

DOI:10.1021/ol050512o

Reference yield:

[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-acetaldehyde (854749-32-9) → C40H56O10 (854749-37-4)

Guidance literature:

Multi-step reaction with 7 steps

1: 80 percent / trimethylsilyl triflate / diethyl ether / -78 °C

2: mCPBA

3: tetra-n-butylammonium fluoride

4: tetrapropylammonium perruthanate; N-methylmorpholine N-oxide

5: 80 percent / DDQ / H₂O; CH₂Cl₂

With tetrapropylammonium perruthennate; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane; water; 5: Pinnick oxidation;

DOI:10.1021/ol050512o

upstream raw materials:

(S)-5-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)pentanal

(4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-2-trimethylsilanylmethyl-oct-1-en-4-ol

[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-acetaldehyde

{2-[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-ethoxy}-tert-butyl-diphenyl-silane