trans-[Pt(C_.tplbond.C-t-Bu)(PPh₂H)2]

Base Information

• Chemical Name: trans-[Pt(C_.tplbond.C-t-Bu)(PPh₂H)2]
• CAS No.: 203063-11-0
• Molecular Formula: C₃₆H₄₀P₂Pt
• Molecular Weight: 729.741
• Mol file: 203063-11-0.mol

Synonyms:

Chemical Property of trans-[Pt(C_.tplbond.C-t-Bu)(PPh₂H)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Pt(C_.tplbond.C-t-Bu)(PPh₂H)2]

There total 1 articles about trans-[Pt(C_.tplbond.C-t-Bu)(PPh₂H)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

2Li(1+)*Pt(C2C(CH3)3)4(2-)=Li2(Pt(C2C(CH3)3)4) + acetone (67-64-1) + diphenylphosphane (829-85-6) → trans-[Pt(C.tplbond.C-t-Bu)(PPh2H)2] (203063-11-0,221564-78-9) + [Pt(CCC(CH3)3)2(P(C6H5)2O)2Li2(H2O)(CH3COCH3)2]2*0.5CH3COCH3

Guidance literature:

With air; In ethanol; acetone; (N2); react. of complex with excess PPh2H, slow pptn. (7 h), stirring filtrate under air (7 h), pptn. of di-Pt complex, recrystn. (acetone);

DOI:10.1039/a705522f

Reference yield: 76.0%

acethylacetonato(1,5-cyclooctadiene)rhodium(I) + trans-[Pt(C.tplbond.C-t-Bu)(PPh2H)2] (203063-11-0,221564-78-9) → cis,cis-[(C.tplbond.C-t-Bu)(PPh2H)Pt(μ-κC(α):η(2)-C.tplbond.C-t-Bu)(μ-PPh2)RhCOD] (233672-72-5)

Guidance literature:

In acetone; byproducts: Hacac; addn. of stoich. amt. of Rh-complex to Pt-complex at -20°C, stirring at 20°C for 5 h (pptn.); collection (filtration), washing (cold Me2CO); elem. anal.;

DOI:10.1021/ic9900049

Reference yield: 62.0%

cis-[(pentafluorophenyl)2 (tetrahydrofurane)2 platinum(II)] + trans-[Pt(C.tplbond.C-t-Bu)(PPh2H)2] (203063-11-0,221564-78-9) → trans,sym-[Pt(μ-κC(α):η(2)-C.tplbond.C-t-Bu)(C6F5)(PPh2H)]2 (233672-68-9)

Guidance literature:

In dichloromethane; equimolar amts., stirring for 20 min; partial evapn., EtOH addn. (pptn.); further crop from mother liquor; elem. anal.;

DOI:10.1021/ic9900049

upstream raw materials:

acetone

diphenylphosphane

Downstream raw materials:

trans,sym-[Pt(μ-κC(α):η(2)-C.tplbond.C-t-Bu)(C6F5)(PPh2H)]2

cis,cis-[(C.tplbond.C-t-Bu)(PPh2H)Pt(μ-κC(α):η(2)-C.tplbond.C-t-Bu)(μ-PPh2)RhCOD]

cis,cis-[(C.tplbond.C-t-Bu)(PPh2H)Pt(μ-κC(α):η(2)-C.tplbond.C-t-Bu)(μ-PPh2)Rh(CO)2]

[Pt(C.tplbond.C-t-Bu)(μ-PPh2)(PPh2H)]2